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PFAS: Last Week Tonight with John Oliver (HBO)

newtboy says...

Actually it’s both. The final forms aren’t stable in the real world, they shed particles that are ingested, vapors inhaled, who knows, they are likely absorbed through the skin from many products.

Assume they aren’t actually toxic, functioning as designed they coat digestive systems and, if the report is to be believed, individual cells in extreme cases, leading to things like digestive issues and vaccinations not working. In developing children, it sounds disastrous…and it’s everywhere and in everyone….often in high levels.

This is akin to a crop that’s mildly toxic, not one adjacent to a pre existing separate toxic weed. You can’t plant this crop without permanently contaminating the field, and adjacent fields, and the local water sources, and to lesser extent anyone who uses the crop. There’s no separate toxic weed here, just a toxic crop we keep planting in new places, making the contamination much much more widespread at constantly increasing levels with no way to clean it up and little knowledge of the long term effects of such contamination. Pretty big gamble to take with the entire planet just so your thin rain coat doesn’t leak, don’t you think? Especially with a non biodegradable easily spread but impossible to remove toxic chemical with relatively unknown cumulative effects and no method whatsoever for removing it from people or the environment….like this one.

bremnet said:

So my contention and the view of many in the end user community is that it's not the final form of some of these compounds that are bad, it's the horrendous messes we leave producing them. We can't unwind our Clock of Dumb, but killing the entire crop just to get rid of the long ago seeded weeds doesn't solve the actual problem, it makes it much, much larger.

Thanks for your comments.

PFAS: Last Week Tonight with John Oliver (HBO)

bremnet says...

Howdy - I don't know if "addressed" is the right word. Commented on, but not given sufficient perspective. Having said that, the problem is incredibly complex, so there should be no expectation that Mr. Oliver's video or any other single thesis on the topic could possibly suffice.

Your "one chemical bond difference" is an appropriate consideration, but with recognition that once we reach on the order of C20-C40 length dispersable or emulsifiable molecules as surfactants / surface energy modifiers, the insoluble polymers come into play, with not 30'ish bonds growing one at a time, but leaping to 20,000 or more. No doubt the pool has already been irreversibly pissed into by the irresponsible producers that convert small molecules into very, very large ones, but with some control, responsibility, and integrity in our industrial process owners (yes, hell just froze over) there is no reason why we could not safely continue to produce the polymeric forms of PFAS. We do so for substantially more toxic chemical conversion processes today.

It's interesting to note the (usual) examples brought forward by others in this post (Teflon cookware), just waiting for someone to mention Gore-Tex, but by far the biggest impact won't be on consumer goods that we all touch regularly and recognize the name brands of, but will be on the industrial / commercial uses of these polymeric families that are pervasive in the systems / processes that we all derive benefit from every day. Ironies exist, that perhaps confuse the "all PFAS are bad" premise ... consider - effectively every seal, gasket and control valve in a water purification plant is most commonly made of a PFAS polymeric compound, PTFE included, all tested to rigorous specifications and compliance by specific agencies that do nothing other than deal with potable water (thankfully not the EPA - it's National Sanitation Foundation (the other NSF), or Water Research Advisory Scheme (WRAS) in the UK etc.) .

So my contention and the view of many in the end user community is that it's not the final form of some of these compounds that are bad, it's the horrendous messes we leave producing them. We can't unwind our Clock of Dumb, but killing the entire crop just to get rid of the long ago seeded weeds doesn't solve the actual problem, it makes it much, much larger.

Thanks for your comments.

newtboy said:

To be fair, most of your complaints were addressed in the piece.

For instance, medical implants, fairly stable, yes, but not in extreme heat like cremation, so as used they’re toxic to the environment despite being considered stable and inert.

The reason to ban them all was also explained, banning one toxic substance at a time means one chemical bond difference and the company can go ahead with Cancer causer 2.0 for a decade until it’s banned for being toxic, and then repeat. It’s how they’ve operated for decades.

I’m fine with outlawing the entire class and putting the onus on the chemical companies to prove any new variants are safe instead of forcing the hamstrung epa to prove they’re unsafe. I also think any company that dumped it into waterways should be instantly and completely forfeited to pay for cleanup. No company has the funds to pay for cleanup, but their assets are at least a start.

Syria's war: Who is fighting and why [Updated]

ChaosEngine says...

I've yet to see any credible sources that it WASN'T a chemical attack.

Meanwhile, organisations like Amnesty and the WHO seem reasonably convinced it was a chemical attack, unless you think they're shills too.

enoch said:

i had read about that possibility.that a bomb had blown up a chemical warehouse.

either way,until i see some evidence,i remain skeptical.

Vantablack can make a flat disk of aluminium float on water

newtboy says...

OK, as I said, I don't know exactly how Vantablack is applied, but nanotubes could easily be incorporated in powder coatings and be totally sealed in the coating.
If Vantablack is grown on the surface, it should be even more 'attached' at the molecular level to that surface, shouldn't it? Once the loose powder was cleaned off, that seems like it would be much better than paint at sticking permanently, no?
A sprayable paint version would have to be mixed with a liquid that makes it sprayable and makes it stick, so I would expect it to be 'sealed' in that liquid once it cures, just like any pigment in any paint. Also, clear coats could seal it in if that's not the case, at least as good as any other toxic paint. EDIT: Since nanofibers can withstand high temperatures, they could even bake on a clear powder coating that's WAY tougher than clear coat to seal it if needed.
Most paints use highly toxic chemicals too. Just because there's no lead doesn't mean it's non toxic....in fact, it might be MORE toxic, just not in the same "brain damaging" way.

I have actually personally worked with nanotubes. I had a friend I worked with that had a carbon fiber business that did dozens of experiments with it for multiple projects, including a carbon fiber bullet and machine-able solid carbon blocks. He'll probably be the one to watch to see how dangerous they are, he rarely used any type of protection and I'm sure he inhaled multiple grams worth of nanotubes in his time, and has them imbedded in his skin all over his body. All of his products used resin to liquefy and harden the nanotubes into the shapes he wanted, so in the end products, it was "sealed" into a non-powder form, but not during production.

ForgedReality said:

Okay first off, powdercoating is different. It's a powder that is closer to glass than paint, and it's cured in an oven which melts it onto the surface. Vantablack is grown on a surface and they recommend it is never used in an application where skin contact is involved as it would be unsafe. The sprayable paint version uses another form of carbon nanotubes in a different structure, which is considered "safer," but there's not enough data on it for me to trust it. They also make no mention of it being "sealed" as you claim.

You can if you want. Lead paint was once considered safe, as was asbestos, and aspartame, and cigarettes (at least publicly). Go for it. But we won't agree.

a brief history of the modern strawberry

newtboy says...

This sounds like another great reason to grow your own produce. Then, with the exception of airborne chemicals you can't avoid, you can know what's gone into your own food, and decide for your self which chemicals are acceptable and which aren't. Strawberries are fairly easy to grow. I have 4 large beds of them, all started from one $3 6pack 5 years ago and grown on cheap, plentiful poo, not man made chemicals. Egg shells and horticulture oil work as good as most pesticides, and do no harm. I still lose 20% to pests, but I just grow 300% more than we can eat, so no problem.
I get not everyone can subsistence farm at home, but almost everyone has a window they can put a potted strawberry in....or a pineberry (a new variety, pineapple flavored strawberries).

They ignored the fact that other crops are grown next to the berries that may absorb the toxic chemicals, and that other chemicals are put on those other crops that also drift to the berries, contaminating them with other poisons. I'm glad they did at least mention direct neighborhood contamination.

Shocking Declassified Docs

NicoleBee says...

Don't worry guys, they didn't just do this to US cities, but the cities of some of their allies, too!

"1950 - 1953: The U.S. Army releases chemical clouds over six American and Canadian cities. Residents in Winnipeg, Canada, where a highly toxic chemical called cadmium is dropped, subsequently experience high rates of respiratory illnesses (Cockburn and St. Clair, eds.)."

ReverendTed (Member Profile)

GeeSussFreeK says...

Safe nuclear refers to many different new gen4 reactor units that rely on passive safety instead of engineered safety. The real difference comes with a slight bit of understanding of how nuclear tech works now, and why that isn't optimal.

Let us first consider this, even with current nuclear technology, the amount of people that have died as a direct and indirect result of nuclear is very low per unit energy produced. The only rival is big hydro, even wind and solar have a great deal of risk compared to nuclear as we do it and have done it for years. The main difference is when a nuclear plant fails, everyone hears about it...but when a oil pipeline explodes and kills dozens, or solar panel installers fall off a roof or get electrocuted and dies...it just isn't as interesting.

Pound per pound nuclear is already statistically very safe, but that isn't really what we are talking about, we are talking about what makes them more unsafe compared to new nuclear techs. Well, that has to do with how normal nukes work. So, firstly, normal reactor tech uses solid fuel rods. It isn't a "metal" either, it is uranium dioxide, has the same physical characteristics as ceramic pots you buy in a store. When the fuel fissions, the uranium is transmuted into other, lighter, elements some of which are gases. Over time, these non-fissile elements damage the fuel rod to the point where it can no longer sustain fission and need to be replaced. At this point, they have only burned about 4% of the uranium content, but they are all "used up". So while there are some highly radioactive fission products contained in the fuel rods, the vast majority is just normal uranium, and that isn't very radioactive (you could eat it and not really suffer any radiation effects, now chemical toxicity is a different matter). The vast majority of nuclear waste, as a result of this way of burning uranium, generates huge volumes of waste products that aren't really waste products, just normal uranium.

But this isn't what makes light water reactors unsafe compared to other designs. It is all about the water. Normal reactors use water to both cool the core, extract the heat, and moderate the neutrons to sustain the fission reaction. Water boils at 100c which is far to low a temperature to run a thermal reactor on, you need much higher temps to get power. As a result, nuclear reactors use highly pressurized water to keep it liquid. The pressure is an amazingly high 2200psi or so! This is where the real problem comes in. If pressure is lost catastrophically, the chance to release radioactivity into the environment increases. This is further complicated by the lack of water then cooling the core. Without water, the fission chain reaction that generates the main source of heat in the reactor shuts down, however, the radioactive fission products contained in the fuel rods are very unstable and generate lots of heat. So much heat over time, they end up causing the rods to melt if they aren't supplied with water. This is the "melt down" you always hear about. If you start then spraying water on them after they melt down, it caries away some of those highly radioactive fission products with the steam. This is what happened in Chernobyl, there was also a human element that overdid all their safety equipment, but that just goes to show you the worst case.

The same thing didn't happen in Fukushima. What happened in Fukushima is that coolant was lost to the core and they started to melt down. The tubes which contain the uranium are made from zirconium. At high temps, water and zirconium react to form hydrogen gas. Now modern reactor buildings are designed to trap gases, usually steam, in the event of a reactor breach. In the case of hydrogen, that gas builds up till a spark of some kind happens and causes an explosion. These are the explosions that occurred at Fukushima. Both of the major failures and dangers of current reactors deal with the high pressure water; but water isn't needed to make a reactor run, just this type of reactor.

The fact that reactors have radioactive materials in them isn't really unsafe itself. What is unsafe is reactor designs that create a pressure to push that radioactivity into other areas. A electroplating plant, for example, uses concentrated acids along with high voltage electricity in their fabrication processes. It "sounds" dangerous, and it is in a certain sense, but it is a manageable danger that will most likely only have very localized effects in the event of a catastrophic event. This is due mainly to the fact that there are no forces driving those toxic chemical elements into the surrounding areas...they are just acid baths. The same goes for nuclear materials, they aren't more or less dangerus than gasoline (gas go boom!), if handled properly.

I think one of the best reactor designs in terms of both safety and efficiency are the molten salt reactors. They don't use water as a coolant, and as a result operate at normal preasures. The fuel and coolant is a liquid lithium, fluoride, and beryllium salt instead of water, and the initial fuel is thorium instead of uranium. Since it is a liquid instead of a solid, you can do all sorts of neat things with it, most notably, in case of an emergency, you can just dump all the fuel into a storage tank that is passively cooled then pump it back to the reactor once the issue is resolved. It is a safety feature that doesn't require much engineering, you are just using the ever constant force of gravity. This is what is known as passive safety, it isn't something you have to do, it is something that happens automatically. So in many cases, what they designed is a freeze plug that is being cooled. If that fails for any reason, and you desire a shutdown, the freeze plug melts and the entire contents of the reactor are drained into the tanks and fission stops (fission needs a certain geometry to happen).

So while the reactor will still be as dangerous as any other industrial machine would be...like a blast furnace, it wouldn't pose any threat to the surrounding area. This is boosted by the fact that even if you lost containment AND you had a ruptured emergency storage tank, these liquid salts solidify at temps below 400c, so while they are liquid in the reactor, they quickly solidify outside of it. And another great benefit is they are remarkably stable. Air and water don't really leach anything from them, fluoride and lithium are just so happy binding with things, they don't let go!

The fuel burn up is also really great. You burn up 90% of what you put in, and if you try hard, you can burn up to 99%. So, comparing them to "clean coal" doesn't really give new reactor tech its fair shake. The tech we use was actually sort of denounced by the person who made them, Alvin Weinberg, and he advocated the molten salt reactor instead. I could babble on about this for ages, but I think Kirk Sorensen explains that better than I could...hell most likely the bulk of what I said is said better by him



http://www.youtube.com/watch?v=N2vzotsvvkw

But the real question is why. Why use nuclear and not solar, for instance?

http://en.wikipedia.org/wiki/Energy_density

This is the answer. The power of the atom is a MILLION times more dense that fossil fuels...a million! It is a number that is beyond what we can normal grasp as people. Right now, current reactors harness less that 1% of that power because of their reactor design and fuel choice.

And unfortunately, renewables just cost to darn much for how much energy they contribute. In that, they also use WAY more resources to make per unit energy produced. So wind, for example, uses 10x more steal per unit energy contributed than other technologies. It is because renewables is more like energy farming.

http://videosift.com/video/TEDxWarwick-Physics-Constrain-Sustainable-Energy-Options


This is a really great video on that maths behind what makes renewables less than attractive for many countries. But to rap it up, finally, the real benefit is that cheap, clean power is what helps makes nations great. There is an inexorable link with access to energy and financial well being. Poor nations burn coal to try and bridge that gap, but that has a huge health toll. Renewables are way to costly for them per unit energy, they really need other answers. New nuclear could be just that, because it can be made nearly completely safe, very cheap to operate, and easier to manufacture (this means very cheap compared to today's reactors as they are basically huge pressure vessels). If you watch a couple of videos from Kirk and have more questions or problems, let me know, as you can see, I love talking about this stuff Sorry if I gabbed your ear off, but this is the stuff I am going back to school for because I do believe it will change the world. It is the closest thing to free energy we are going to get in the next 20 years.

In reply to this comment by ReverendTed:
Just stumbled onto your profile page and noticed an exchange you had with dag a few months back.
What constitutes "safe nuclear"? Is that a specific type or category of nuclear power?
Without context (which I'm sure I could obtain elsewise with a simple Google search, but I'd rather just ask), it sounds like "clean coal".

'Apocalyptic' island of waste in the Maldives

kceaton1 says...

You think they'd have learned by MANY of the areas of the world that have found extremely better ways to handle waste than just dumping it in one massive site (even here in the U.S.; I remember having massive dumps in the 80's in Utah, but they're long gone now). Maybe it's temporary, but the fact that all the waste isn't separated, with hazardous and toxic chemicals not being separated is unreal in a semi-well to do country.

They'll have to restore the whole area to rid it of the toxic sludge that'll be made, let alone what WILL go into the water once it hits the water line in that sand. Ick.

Joe Rogan Slams Dr. Drew's Views On Pot

Auger8 says...

I can immediately tell this is propaganda by the simple statement that THC causes physical withdrawal symptoms, I'm sorry but that is complete and utter BS. I have used pot and and stopped using it many times in my life and it's no different than eating hamburgers one day and not eating hamburgers another day, ya I might get a craving for a burger sometimes but it doesn't cause physical pain when I don't indulge that craving. Pot is the same way. I'm guilty of experimenting with many drugs over the years and I can say with certainty that Pot is absolutely harmless in terms on how addicting it is. It's no different that coffee, cokes, red meat, or fatty foods. And even caffeine causes massive headaches when you stop using it. And I would much rather smoke a joint than drink alchohol or smoke cigarettes. Cigarettes have something like 200+ toxic chemicals(Pot has just one THC) in them and they DO cause physical withdrawal symptoms, and so does alchohol(DTs can actually kill a person). THC causes nothing even remotely like withdrawal symptoms, and people like Dr. Drew who I'm sure has never used a drug in his life couldn't possibly know that. I forgive them their ignorance but not for spreading lies pushed out by government owned agencies whose only agenda is to make money.

What is the most dangerous chemical you've worked with?

ghark says...

The thing I hated the most in the lab was having to constantly deal with formaldehyde - a pretty potent carcinogen. It's used in tissue preservation, so anytime you want to extract some DNA/RNA from formalin fixed paraffin embedded (FFPE) tissue you end up getting a dose of it.

The strangest thing is how in our chemistry labs all the waste chemicals from all our experiments had to be put into one big jar, so there would be this viscous, almost gooey mass of this silvery-orange-black'ish sort of toxic waste which was a combination of all the 30-40 different (already toxic) chemicals put together. That would then need to sit in the lab for a month until waste collection day arrived.

Ron Paul to Santorum: You're sooooo sensitive!

ghark says...

Aye I agree that not hurting people is a worthy cause, but if you follow that line of thinking, once again you will find inconsistency. For example, if he truly doesn't want to hurt people, why did he try to have the Occupational Safety and Health Act of 1970 repealed - twice.
http://thomas.loc.gov/cgi-bin/bdquery/z?d096:h.r.2310:
http://thomas.loc.gov/cgi-bin/bdquery/z?d094:h.r.13264:

Wouldn't having less safety at work result in more harm to workers, and even deaths?

How about his stance on the environment, would a degraded, polluted environment lead to harm? Quite possibly, and he's sponsored more than a half dozen bills to try to get rid of, or limit legislation protecting it, including a bill to repeal the Soil and Water Conservation Act of 1977.
http://thomas.loc.gov/cgi-bin/bdquery/z?d096:h.r.7079:

There are plenty of studies that demonstrate a scientifically significant correlation between pesticide exposure and cancers, birth defects and spontaneous abortions. Look up carbaryl, atrazine and benomyl-carbendazim to name a few, if he truly wanted to avoid doing harm, shouldn't he focus on legislation that tightens up the use of toxic chemicals in the food chain so that the seasonal and migrant workers (especially) might have improved health outcomes?

What about his handling of the Florida oil spill, the ecosystem there got devastated and there will be ongoing health consequences for not just the locals. His reaction was that there should be less oversight by the Government and instead there should be promises by the corporations to make good any damages with the populations they affect. That's not just an example of how his principles could harm people but it's an example of libertarianism gone crazy. His sponsorship of the H.R.2415 and H.R.4004 bills back this up, both of them incentivize off-shore drilling.
http://www.ronpaul.com/2010-06-16/ron-paul-defends-obama-on-bp-oil-spill-and-himself-on-owning-gold/

He takes the stance that he 'doesn't want to hurt people because he's then able to get a lot of anti-abortion supporters to vote for him, or in other words, he's doing a good job of being a politician. In addition, he's deciding what is right and what is wrong for the people that have other opinions and may wish to express those opinions in the form of exercising the right to make an informed decision about their future family - I don't call that libertarianism.

"Non-Violent" UC Davis Protestors Pepper Sprayed

ghark says...

The policemen who used the pepper spray AND their bosses need to be named and shamed, if they haven't already - that's just demonstrably inhumane and unjustified.

Oh look, there's some humans linking arms, let's spray toxic chemicals into their eyeballs.

Pepper Spray Victim Dorli Rainey - Countdown 11-16-2011

Alternate 'Return of the Jedi' ending - Misjudged Effects

Asmo says...

In the SWG MMO you actually find large chunks of the DStar's superstructure in the Endor zone where it crashed to the planet.

If we're going to accept the movie as canon, there's really not much left in that explosion. Conveniently reasserting disbelief to extrapolate environmental damage is a bit of a stretch... =)

But what the hell, you can only imagine how many toxic chemicals etc were released in to the environment from the sabotage of the shield generator station... *grin*

Peter Schiff’s 3 Reasons Why Financial Reform Will Fail

NetRunner says...

@blankfist, since you seem to want my thoughts on this (but for some reason, wanted to edit the comment to look like you were just clearing your throat), I'll give you my rebuttal.

I'll take his three points in reverse order.

#3 about regulatory uncertainty is one of these universal conservative economic fantasies. There's no evidence that this really has any kind of macroeconomic effect. Certainly the usual conservative and business advocacy groups always get a laundry list of businessmen to all line up and say how they won't be able to function if they have to pay compensation to workers injured on the job, have to check to see if the products they produce are poisonous or otherwise unsafe, can't dump toxic chemicals into lakes and rivers, can't use slave labor, etc, etc. They always fight against efforts to stop them from being able to leverage negative market externalities for extra profit.

#2 The Yahoo Finance link itself debunks this, because what Schiff says is a flat-out lie. Here's what that link says:

In contrast to Schiff's warning, the law does the following, according to Reuters:

“The bill would set up an "orderly liquidation" process that the government could use in emergencies, instead of bankruptcy or bailouts, to dismantle firms on the verge of collapse.

“The goal is to end the idea that some firms are 'too big to fail' and avoid a repeat of 2008, when the Bush administration bailed out AIG and other firms but not Lehman Brothers. Lehman's subsequent bankruptcy froze capital markets.

“Under the new rule, firms would have to have 'funeral plans' that describe how they could be shut down quickly.”

Liberal critics also question whether the bill addresses "Too Big to Fail", but they're talking about limits on the overall size of banks.

#1 I've covered this fantasy of Schiff's about the nature of the crisis before. Here are two quick points I always make, which you never respond to: low interest rates don't create moral hazard, and Fannie and Freddie weren't even remotely the biggest players in the subprime mortgage-backed security space, much less the chief source of moral hazard.

All the moral hazard was created by the financial industry thinking it had found a way to insulate itself from the risks involved in bad mortgages using CDO's and CDS's -- without relying on government backing of any kind.

I'm happy to go into much more depth on #1 if you like, but you've never really demonstrated that you have any interest in listening to what I have to say on the topic with anything like an open mind.

Oh, and liberals agree that this bill doesn't really do enough in addressing the underlying problems that led to the crisis (the real ones). Basically, they say there's not enough rating agency reform, no leverage caps on investment banks, no Glass-Steagall separation of traditional and investment banks, no commitment to break up banks that grow beyond a certain size, etc.

In fact, from what I've read, the strongest part of this bill is exactly the part Schiff lied about -- it should prevent future Congresses from being forced to do taxpayer-funded bailouts. Instead, it'll be like the standard FDIC process for failed banks, only scaled up to deal with corporations of this size and complexity. Under that process, the bank shareholders, owners, and management get wiped out and fired, but the bank's creditors and depositors are made whole. The bank fails, but it doesn't take a huge chunk of the economy with it when it goes.



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