I have seen and remember all of these but two. The one with Klaus Kinski and the one where the german officer stabs a guy in the face repeatedly, are the two I've never seen.
Many of the villians I could name, many of them are on the tip of my tongue and will probably drive me nuts trying to come up with the names. I could name the actors or the movies, but the villians names are tough ( without doing research).
This is a great list, and I would like to start off a discussion by saying... The Wicked Witch of the West should be on here, I've hated that bitch as far back as I can recall.

Awww there's soo much more to that bit that's not here. Like the part where she plays the Wicked Witch song from the Wizard of Oz.

Ding Dong! The Witch is dead. Which old Witch? The Wicked Witch!

NO! Begone with you, wicked witch of the politic-sift worlds!

In reply to this comment by nomino:
Please watch this: http://www.videosift.com/video/Economic-Hitmen-Assassinations-in-Ecuador-Panama-Guatemala

Same here! Just imagine the suprise of the Munchkins in Oz, as a ship full of Chinese sailors is dumped on the Wicked Witch of the east The fun could well be endless...

*bang bong the witch is dead ...who? THE WICKED WITCH ..the wicked witch is dead..

well, that this clip has as many votes as it does says something about us, and the news as entertainment.

i like when the guest calls her 'missy' just like the wicked witch.